Instituto de Biomoléculas (INBIO)
Instituto de investigación
PEDRO SIXTO
VALERGA JIMENEZ
Investigador en el periodo 1980-2019
Publicaciones en las que colabora con PEDRO SIXTO VALERGA JIMENEZ (77)
2021
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Activation of Dichloromethane by a Bis-NHC Cp*Ru Complex: Formation of a Pentamethyl(chloromethyl)cyclopentadiene Ligand
Organometallics, Vol. 40, Núm. 15, pp. 2405-2408
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Methylene-Linked Bis-NHC Half-Sandwich Ruthenium Complexes: Binding of Small Molecules and Catalysis toward Ketone Transfer Hydrogenation
Organometallics, Vol. 40, Núm. 6, pp. 792-803
2018
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Cationic R-Substituted-Indenyl Nickel(II) Complexes of Arsine and Stibine Ligands: Synthesis, Characterization, and Catalytic Behavior in the Oligomerization of Styrene
European Journal of Inorganic Chemistry, Vol. 2018, Núm. 5, pp. 597-607
2016
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Activation of Propargyl Alcohols by TpRu Complexes Bearing a Bidentate NHC Ligand
Organometallics, Vol. 35, Núm. 3, pp. 388-399
2015
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Atom-economical synthesis of the versatile ruthenium precursor [TpRuCl(COD)] (Tp = hydrotris(pyrazol-1-yl)borate) discloses a diamine ligand dealkylation process
Organometallics, Vol. 34, Núm. 5, pp. 1001-1004
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First examples of neutral and cationic indenyl nickel(II) complexes bearing arsine or stibine ligands: Highly active catalysts for the oligomerisation of styrene
Dalton Transactions, Vol. 44, Núm. 39, pp. 17015-17019
2014
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Counteranion-dependent reaction pathways in the protonation of cationic ruthenium-vinylidene complexes
Organometallics, Vol. 33, Núm. 10, pp. 2549-2560
2013
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Counteranion and solvent assistance in ruthenium-mediated alkyne to vinylidene isomerizations
Inorganic Chemistry, Vol. 52, Núm. 15, pp. 8919-8932
2011
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Facile O-H bond activation in alcohols by [Cp*RuCl( iPr2PSX)] (X = pyridyl, quinolyl): A route to ruthenium(IV) hydrido(alkoxo) derivatives
Inorganic Chemistry, Vol. 50, Núm. 24, pp. 12399-12401
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Internal alkyne isomerization to vinylidene versus stable π-Alkyne: Theoretical and experimental study on the divergence of analogous Cp*Ru and TpRu systems
Organometallics, Vol. 30, Núm. 15, pp. 4014-4031
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Nucleophilic addition reactions to allenylidene complexes of ruthenium bearing hemilabile P,N ligands: Isolation of the vinylcarbene complex [Cp*Ru-CHCH-CPh2(iPr2PNHPy)][PF 6]
Organometallics, Vol. 30, Núm. 4, pp. 726-737
2010
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Isomerization of internal alkynones to vinylidenes in tris(pyrazolyl)borate ruthenium complexes. Solution and solid-state kinetics
Organometallics, Vol. 29, Núm. 7, pp. 1740-1749
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Proton-transfer reactions to half-sandwich ruthenium trihydride complexes bearing hemilabile P,N ligands: Experimental and density functional theory studies
Inorganic Chemistry, Vol. 49, Núm. 14, pp. 6035-6057
2009
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Oligomerization of styrenes mediated by cationic allyl nickel complexes containing triphenylstibine or triphenylarsine
Dalton Transactions, pp. 1842-1852
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Reactivity of the ruthenium hydride complex [Ru{K3-H,S,S-HB(mt) 3}H(PPh3)2] (HB(mt)3 = hydrotris(methimazolyl)borate): Catalytic dimerization of 1-alkynes and proton transfer reactions
Organometallics, Vol. 28, Núm. 9, pp. 2787-2798
2007
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Half-sandwich hydride complexes of ruthenium with bidentate phosphinoamine ligands: Proton-transfer reactions to [(C5R5)RuH(L)] [R = H, Me; L = dippae, (R,R)-dippach]
Inorganic Chemistry, Vol. 46, Núm. 3, pp. 1001-1012
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Oligomerization and regioselective hydrosilylation of styrenes catalyzed by cationic allyl nickel complexes bearing allylphosphine ligands
Journal of the Chemical Society. Dalton Transactions, pp. 3000-3009
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TpRu complexes as recoverable Lewis acid catalysts for enantioselective solvent-free cycloaddition reactions (Tp = hydrotris(pyrazolyl)borate)
Journal of Molecular Catalysis A: Chemical, Vol. 261, Núm. 1, pp. 64-72
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γ-Substituted Vinylidene, Chroman-2-ylidene, and Hexahydrochromen-2- ylidene from Ruthenium Allenylidene/Alkenylcarbyne Complexes
Organometallics, Vol. 26, Núm. 17, pp. 4300-4309
2006
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Ruthenium allenylidene/alkenylcarbyne complexes triggering keto-enol tautomerism: An alternative approach to γ-keto vinylidenes from simple ketones and 1,3-dicarbonyl compounds
Organometallics, Vol. 25, Núm. 16, pp. 4019-4025