Tratamiento de conservación a gran escala de piezas de artillería pesada de hierro fundido y procedencia subacuática. Procedimientos metodológicos

  1. Inmaculada Sánchez Pedreño 1
  2. Ignacio Salas Pardo de Donlebún 1
  3. Santos García Trigo 1
  4. Bethencourt Núñez, Manuel
  5. Juan Francisco García Amado
  1. 1 Aula3 Actuaciones Integrales sobre el Patrimonio S.L.
  2. 2 Airbus Operations
  3. 3 Universidad en el Departamento de Ciencia de los Materiales e Ingeniería Metalúrgica y Química Inorgánica de la Universidad de Cádiz
Zeitschrift:
Ge-conservación

ISSN: 1989-8568

Datum der Publikation: 2022

Nummer: 21

Seiten: 16-28

Art: Artikel

DOI: 10.37558/GEC.V21I1.970 DIALNET GOOGLE SCHOLAR lock_openDialnet editor

Andere Publikationen in: Ge-conservación

Zusammenfassung

This paper describes the simultaneous cleaning and chloride extraction, through electrolysis treatment, of 17 underwater-origin cast iron barrels from XVIII century coming from a casual find. Within a low-budget context, customized vats were made. Specific tools for the cleaning of the pieces were also developed: a high-precision drill to access the bore of the barrels and rotating work bases. Moreover, a new stabilization technique for large casting pieces was applied by wrapping them in absorbent material impregnated in NaOH. The selection of the current density for the electrolysis treatment was established by a previous test, which demonstrated the higher efficiency of 50 µAcm¯ ² against 1000 µAcm¯ ². The description of the tasks performed, along with the novel methodological procedures provided, constitute a valuable information for future actions in the field of large-scale conservation of Underwater Cultural Heritage (UCH).

Informationen zur Finanzierung

A todas y cada una de las personas que formaron parte del equipo de trabajo, a los revisores an?nimos por la aportaci?n de perspectiva que sirvi? para mejorar el trabajo y al Laboratorio de Estudios y Conservaci?n del Patrimonio Hist?rico (LEC-PH) de la UCA, financiado por FEDER-MICIN EQC2018-004947-P.

Geldgeber

Bibliographische Referenzen

  • GOBIERNO DE MÉXICO, INSTITUTO NACIONAL DE ANTROPOLOGÍA E HISTORIA (INAH). “Aplican tratamiento a cañones centenarios de Campeche”. https://inah.gob.mx/boletines/1065-aplican-tratamiento-a-canones-centenarios-de-campeche
  • BERNAL, J.D., DASGUPTA, D., RMACKAY, A.L. (1959). “The oxides and hydroxides of iron and their structural interrelations”. En Clay Miner. Bull, 4: 15–30.
  • BERTHOLON, R AND RELIER C. (1990). “Les métaux archéologiques”. En La conservation en archéologie. Méthodes et pratique de la conservation-restauration des vestiges archéologiques, Masson, Paris, France, 163-22.
  • BERTHOLON, R. (2001). “Nettoyage stabilisation de la corrosión per électrolyse”. En La conservation des métaux, Volfovsky, C (Coord.) París. CNRS EDITIONS, 83-101.
  • BETHENCOURT, M Y ZAMBRANO, L. (2011). “Análisis de cloruros en la zona grafitizada de un cañón de hierro procedente del pecio Bucentaure (La Caleta, Cádiz) tratado mediante polarización catódica de baja intensidad”. En IV Congreso Latinoamericano de Conservación y Restauración de Metal, Madrid, 256-270. https://doi.org/10.13140/2.1.4906.7849
  • BURSHNEVA, S. AND SMIRNOVA, N., in: G. Eggert, B. Schmutzler (Eds.), Archaeological Iron Conservation Colloquium 2010 –Extended Abstracts Session 3: Alkaline Chloride Extraction, State Academy of Art and Design, Extended Abstracts, 24th to 26th June Stuttgart, Germany 2010.
  • CARLIN, W., KEITH, D. AND RODRÍGUEZ, J. (2001). “Less is more: measure of chloride removal rate from wrought iron artifacts during electrolysis”. En Studies in Conservation, 46: 68-76.
  • COELHO, J.C. (2010), “Estudo da eficiência de técnicas electroquímicas na remoção de cloretos em amostras de uma bala de canhão proveniente de um naufrágio do séc. XVIII”, Dissertações de Mestrado, Repositório da Universidade de Lisboa, Comunidades & Colecções, Faculdade de Ciências (FC).
  • COELHO, J.C., OLIVEIRA, C.M., CARVALHO M. D. AND FONSECA I.T.E. (2014). “The efficiency of electrochemical methods for the removal of chloride ions from iron marine archaeological objects: A comparative study”. En Materials and Corrosion, 65(1): 38-44. https://doi.org/10.1002/maco.201206584
  • CORNELL, R. AND GIOVANOLI, R. (1986). “Factors that govern the formation of multi-domainic goethites”. En Clays and Clay Minerals, 34(5): 557–564. https://doi.org/10.1346/CCMN.1986.0340509
  • DEGRIGNY, A., (2010) “Use of electrochemical techniques for the conservation of metal artefacts: A review”, En Journal of Solid State Electrochemistry 14(3):353-361. https://doi.org/10.1007/s10008-009-0896-0
  • DOMÉNECH-CARBÓ A., DOMÉNECH-CARBÓ M.T. AND COSTA V. (2009), “Electrochemical methods in Archaeometry, Conservation and Restoration”, En Series: Monograph in Electrochemistry (Ed. F. Scholz), Springer-Verlag Berlin Heidelberg, Berlin, 166.
  • GÉNIN J.M.R., BOURRIÉ G., TROLARD F., ABDELMOULA M., JAFFREZIC A., REFAIT P., MAITRE V., HUMBERT B., HERBILLON A. (1998). “Thermodynamic equilibria in aqueous suspensions of synthetic and natural Fe(II)-Fe(III) green rusts: occurrences of the mineral in hydromorphic soils”. En Environ Sci. Technol, 32: 1058-1068. https://doi.org/10.1021/es970547m
  • GÉNIN, J.M.R.; OLOWE, A. A.; RÉSIAK, B.; BENBOUZID-ROLLET, N. D.; CONFENTE, M.; PRIEUR, D. (1993). “Marine corrosion of stainless steels: chlorination, and microbial effects”. En European Federation Corrosion Series; The Institute of Materials: London, 10:162-166.
  • GÉNIN J.M.R., ABDELMOULA, M., RUBY, C AND UPADHYAY C. (2006). “Speciation of iron; characterisation and structure of green rusts and FeII–III oxyhydroxycarbonate fougerite”. En C. R. Geoscience 338: 402-419. https://doi.org/10.1007/s10751-011-0500-8
  • GIL, M.L.A., SANTOS, A., BETHENCOURT, M., GARCÍA, T., FERNÁNDEZ-BASTERO, S., VELO, A., GAGO-DUPOR L. (2003). “Use of X-ray and other techniques to analyse the phase transformation induced in archaeological cast iron after its stabilisation by the electrolytic method”. En Analytica Chimica Acta, 494: 245–254. https://doi.org/ 10.1016/j.aca.2003.08.012
  • HAMILTON, D. (1997). “Basic Methods of Conserving Underwater Archaeological Material Culture”. Nautical Archaeology Program, Department of Anthropology, Texas, A&M University.
  • KERGOURLAYA F., RÉGUERB S., NEFFA D., FOYA E., PICCAB F.E., SAHEBC M., HUSTACHEB S., MIRAMBETD F., DILLMANNA P. (2018). “Stabilization treatment of cultural heritage artefacts: In situ monitoring of marine iron objects dechlorinated in alkali solution”. En Corrosion Science, 132: 21-34. https://doi.org/10.1016/j.corsci.2017.12.028
  • LARA-MARTÍN P.A., GÓMEZ-PARRA A., PETROVIC M., BARCELÓ D., GONZÁLEZ-MAZO E. (2005). “Distribution of organic pollutants in coastal sediments of Cádiz Bay (SW Spain)”. En Ciencias Marinas 31(1B): 203–212. https://doi.org/10.7773/cm.v31i12.95
  • MINISTERIO ESPAÑOL DE CULTURA Y DEPORTE. “Proyecto Nuestra Señora de las Mercedes”. http://www.culturaydeporte.gob.es/mnarqua/investigacion/proyectos/nsm.html [Consulta: 05/11/2019].
  • OLOWE, A. A.; BAUER, PH.; GÉNIN, J.-M. R.; GUE´ZENNEC, J. (1989). “Moessbauer Effect Evidence of the Existence of Green Rust 2 Transient Compound from Bacterial Corrosion in Marine Sediments”. En Corrosion, 45 (3): 229–235. https://doi.org/10.5006/1.3577848
  • PLENDERLEITH, H. J. (1956). The Conservation of Antiquities and Works of Art. London. Oxford University Press.
  • POZO A., J. S.; RIVAS, T.; LÓPEZ, A. J.; FIORUCCI, M. P.; RAMIL, A. (2016). “Effectiveness of granite cleaning procedures in cultural heritage: A review”. Sci. Total Environ, 571: 1017–1028. https://doi.org/ 10.1016/j.scitotenv.2016.07.090
  • RAMOS GIL, A. (2015). “Recuperación de 16 cañones del siglo XVIII, y su puesta en valor en las murallas de Cádiz”. En Actas del II Congreso de Conservación y Restauración del Patrimonio Metálico. MetalEspaña 2015. Real Casa de Moneda, Segovia, 200-205.
  • REFAIT, PH.; GÉNIN, J. M. R. (1997). “Mechanisms of oxidation of Ni(II)-Fe(II) hydroxides in chloride-containing aqueous media: role of the pyroaurite-type Ni-Fe hydroxychlorides” En Clay Minerals 32(4): 597-613
  • RÉMAZEILLES C., NEFF D., KERGOURLAY F., FOY E., CONFORTO E., GUILMINOT E., REGUER S., REFAIT PH., DILLMANN PH. (2009). “Mechanisms of long-term anaerobic corrosion of iron archaeological artefacts in seawater”. En Corrosion Science, 51: 2932-2941. https://doi.org/10.1016/j.corsci.2009.08.022
  • RIMMER, M., WATKINSON, D. AND WANG, Q. (2013). “The impact of chloride desalination on the corrosion rate of archaeological iron”. En Studies in Conservation, 58(4): 326-337. https://doi.org/ 10.1179/2047058412Y.0000000068
  • SCMUTZLER B. AND EBINGER-RIST, B.N. (2008). “The conservation of iron objects in archaeological preservation – Application and further development of alkaline sulphite method for conservation of large quantities of iron finds”. En Materials and Corrision, 59(3), 248-245. https://doi.org/10.1002/maco.200804109
  • SELWYN, L. (2004) “Overview of archaeological iron: the corrosion problem, key factors affecting treatment, and gaps in current knowledge”, Metal 04: Proceedings of the International Conference on Metals Conservation, Canberra, Australia, 4-8 October 2004, 294-306.
  • STAMPFL, P. P. (1969). “Ein basisches eisen-II-III-karbonat in rost”. En Corrosion Science, 9:185-187. https://doi.org/10.1016/S0010-938X(69)80029-6
  • UNESCO (2001). Convención de la Unesco. La Protección del Patrimonio Cultural Subacuático. París. http://portal.unesco.org/es/ev.php-URL_ID=13520&URL_DO=DO_TOPIC&URL_SECTION=201.html[Consulta: 08/10/2019].
  • VENERANDA, M., PRIETO-TABOADA, N., CARRERO, J.A. COSTANTINI, I., LARRAÑAGA, A., CASTRO, K., ARANA G. AND MADARIAGA, J.M. (2021) “Development of a novel method for the in-situ dechlorination of immovable iron elements: optimization of Cl− extraction yield through experimental design”. En Scientific Reports ,11:10789. https://doi.org/10.1038/s41598-021-90006-y
  • WANG, Q., (2007) An Investigation of Deterioration of Archaeological Iron”. En Studies in Conservation, 52(2: 125-134. https://doi.org/ 10.1179/sic.2007.52.2.125
  • WANG, Z., XU, C., CAO, X., AND XU, B. (2007). “The Morphology, Phase Composition and Effect of Corrosion Product on Simulated Archaeological Iron”. En Chinese Journal of Chemical Engineering, 15(3): 433-438. https://doi.org/10.1016/S1004-9541(07)60104-9
  • WATKINSON, D. AND A. AL-ZAHRANI, A. (2008), “Towards quantified assessment of aqueous chloride extraction methods for archaeological iron: De‐oxygenated treatment environments”. En The Conservator, 31: 75-86. https://doi.org/10.1080/01410096.2008.9995234