Pt, Rh AND Pd NANO-PARTICLES SUPPORTED ON Ce0.68Zr0.32O2 MIXED OXIDE FOR APPLICATION IN AUTOMOTIVE THREE-WAY CATALYSTS

  1. R.T. Baker 2
  2. S. Bernal 1
  3. J.J. Calvino 1
  4. J.M. Gatica 1
  5. C. López-Cartes 1
  6. J.A. Pérez-Omil 1
  1. 1 Universidad de Cádiz
    info

    Universidad de Cádiz

    Cádiz, España

    ROR https://ror.org/04mxxkb11

  2. 2 Division of Physical and Inorganic Chemistry, University of Dundee, Nethergate, Dundee DDl4HN, United Kingdom.
Actas:
Electron Microscopy and Analysis Group Conf. EMAG2001, Dundee, 2001

ISSN: 0951-3248

Año de publicación: 2001

Volumen: 168

Páginas: 417-420

Tipo: Aportación congreso

Resumen

Automotive catalyst samples consisting of Rh, Pt and Pd particles súpported on a texturally stable Ce0.68Zro3202 mixed oxide support were studied by High Resolution Transition Electron Microscopy (HRTEM) after reduction at a range of temperatures. The majority of metal particles had regular morphologies and were crystallographically aligned with the oxide support. At higher reduction temperatures, sorne unusual effects were observed in a minority of metal particles. These included decoration of the metal particles by the support material and the formation of "pedestals" of support material directly beneath sorne metal particles.