Pt, Rh AND Pd NANO-PARTICLES SUPPORTED ON Ce0.68Zr0.32O2 MIXED OXIDE FOR APPLICATION IN AUTOMOTIVE THREE-WAY CATALYSTS
- R.T. Baker 2
- S. Bernal 1
- J.J. Calvino 1
- J.M. Gatica 1
- C. López-Cartes 1
- J.A. Pérez-Omil 1
-
1
Universidad de Cádiz
info
- 2 Division of Physical and Inorganic Chemistry, University of Dundee, Nethergate, Dundee DDl4HN, United Kingdom.
ISSN: 0951-3248
Año de publicación: 2001
Volumen: 168
Páginas: 417-420
Tipo: Aportación congreso
Resumen
Automotive catalyst samples consisting of Rh, Pt and Pd particles súpported on a texturally stable Ce0.68Zro3202 mixed oxide support were studied by High Resolution Transition Electron Microscopy (HRTEM) after reduction at a range of temperatures. The majority of metal particles had regular morphologies and were crystallographically aligned with the oxide support. At higher reduction temperatures, sorne unusual effects were observed in a minority of metal particles. These included decoration of the metal particles by the support material and the formation of "pedestals" of support material directly beneath sorne metal particles.