Publications (21) EMILIO BUSTELO GUTIERREZ publications

2017

  1. Kinetic Analysis and Mechanism of the Hydrolytic Degradation of Squaramides and Squaramic Acids

    Journal of Organic Chemistry, Vol. 82, Núm. 4, pp. 2160-2170

2016

  1. Cycloaddition of alkynes to diimino Mo3S4 cubane-type clusters: A combined experimental and theoretical approach

    New Journal of Chemistry, Vol. 40, Núm. 9, pp. 7872-7880

  2. Kinetics Aspects of the Reversible Assembly of Copper in Heterometallic Mo3CuS4 Clusters with 4,4′-Di-tert-butyl-2,2′-bipyridine

    Inorganic Chemistry, Vol. 55, Núm. 19, pp. 9912-9922

2015

  1. On the Critical Effect of the Metal (Mo vs. W) on the [3+2] Cycloaddition Reaction of M3S4 Clusters with Alkynes: Insights from Experiment and Theory

    Chemistry - A European Journal, Vol. 21, Núm. 42, pp. 14823-14833

2011

  1. Internal alkyne isomerization to vinylidene versus stable π-Alkyne: Theoretical and experimental study on the divergence of analogous Cp*Ru and TpRu systems

    Organometallics, Vol. 30, Núm. 15, pp. 4014-4031

2010

  1. Isomerization of internal alkynones to vinylidenes in tris(pyrazolyl)borate ruthenium complexes. Solution and solid-state kinetics

    Organometallics, Vol. 29, Núm. 7, pp. 1740-1749

2009

  1. Allenylidene/Alkenylcarbyne synthesis and reactivity in ruthenium complexes with monodentate phosphine ligands

    Organometallics, Vol. 28, Núm. 5, pp. 1546-1557

2007

  1. Activation of mononuclear arene ruthenium complexes for catalytic propargylation directly with propargyl alcohols

    Advanced Synthesis and Catalysis, Vol. 349, Núm. 6, pp. 933-942

  2. γ-Substituted Vinylidene, Chroman-2-ylidene, and Hexahydrochromen-2- ylidene from Ruthenium Allenylidene/Alkenylcarbyne Complexes

    Organometallics, Vol. 26, Núm. 17, pp. 4300-4309

2006

  1. Ruthenium allenylidene/alkenylcarbyne complexes triggering keto-enol tautomerism: An alternative approach to γ-keto vinylidenes from simple ketones and 1,3-dicarbonyl compounds

    Organometallics, Vol. 25, Núm. 16, pp. 4019-4025

2005

  1. An opened route to 1,3-dimethylenecyclobutanes via sequential ruthenium-catalyzed [2 + 2] cycloaddition of allenyl boronate and palladium suzuki coupling

    Journal of the American Chemical Society, Vol. 127, Núm. 33, pp. 11582-11583

  2. Mononuclear ruthenium catalysts for the direct propargylation of heterocycles with propargyl alcohols

    Advanced Synthesis and Catalysis, Vol. 347, Núm. 2-3, pp. 393-397

2003

  1. First x-ray characterization and theoretical study of π-alkyne, alkynyl-hydride, and vinylidene isomers for the same transition metal fragment [Cp*Ru(PEt3)2]+

    Journal of the American Chemical Society, Vol. 125, Núm. 11, pp. 3311-3321

2002

  1. Reactions of RuCp and RuCp* allyl carbene complexes: Products derived from activation of phenyl, cyclohexyl, and methyl C-H bonds in PPh3, PCy3, and Cp* ligands

    Organometallics, Vol. 21, Núm. 14, pp. 2912-2920

  2. Reactivity of the electron-rich allenylidene-ruthenium complexes [Cp*Ru{=C=C=C(R)Ph}(dippe)][BPh4] (R = H, Ph). X-ray crystal structure of a novel dicationic ruthenium carbyne (Cp* = C5Me5; dippe = 1,2-bis(diisopropylphosphine)ethane)

    Organometallics, Vol. 21, Núm. 9, pp. 1903-1911

2001

  1. Hydrido(3-hydroxyalkynyl) complexes as intermediates in the activation of propargyl alcohol derivatives by [Cp*RuCl(dippe)] [Cp* = C5Me5, dippe = 1,2-bis(diisopropylphosphanyl)ethane]

    European Journal of Inorganic Chemistry, pp. 2391-2398

2000

  1. Analysis of the solid-state rearrangement of hydrido-alkynyl ruthenium complexes to their vinylidene tautomers

    Monatshefte fur Chemie, Vol. 131, Núm. 12, pp. 1311-1320

  2. Reaction of alkynes with [RuCp(CO)(CH3CN)2]+ and [RuCp*(CO)(CH3CN)2]+. Convenient synthesis of ruthenium cyclopentadienone complexes

    Organometallics, Vol. 19, Núm. 25, pp. 5384-5391

1999

  1. Activation of Alkynols by [Cp*RuCl(PEt3)2]: New Intermediates and Alternative Dehydration Products. X-ray Crystal Structures of [Cp*Ru{=C=CHC(=CH2)Ph}(PEt3)2][BPh 4], [Cp*Ru(=C=C=CPh2)(PEt3)2][BPh 4]

    Organometallics, Vol. 18, Núm. 22, pp. 4563-4573

  2. Activation of alkynols by half-sandwich ruthenium complexes: isolation of hydroxyalkynyl(hydrido) and hydroxyvinylidene derivatives

    Organometallics, Vol. 18, Núm. 6, pp. 950-951