Publications by the researcher in collaboration with PEDRO SIXTO VALERGA JIMENEZ (14)

2011

  1. Internal alkyne isomerization to vinylidene versus stable π-Alkyne: Theoretical and experimental study on the divergence of analogous Cp*Ru and TpRu systems

    Organometallics, Vol. 30, Núm. 15, pp. 4014-4031

2010

  1. Isomerization of internal alkynones to vinylidenes in tris(pyrazolyl)borate ruthenium complexes. Solution and solid-state kinetics

    Organometallics, Vol. 29, Núm. 7, pp. 1740-1749

2009

  1. Allenylidene/Alkenylcarbyne synthesis and reactivity in ruthenium complexes with monodentate phosphine ligands

    Organometallics, Vol. 28, Núm. 5, pp. 1546-1557

2007

  1. γ-Substituted Vinylidene, Chroman-2-ylidene, and Hexahydrochromen-2- ylidene from Ruthenium Allenylidene/Alkenylcarbyne Complexes

    Organometallics, Vol. 26, Núm. 17, pp. 4300-4309

2006

  1. Ruthenium allenylidene/alkenylcarbyne complexes triggering keto-enol tautomerism: An alternative approach to γ-keto vinylidenes from simple ketones and 1,3-dicarbonyl compounds

    Organometallics, Vol. 25, Núm. 16, pp. 4019-4025

2003

  1. First x-ray characterization and theoretical study of π-alkyne, alkynyl-hydride, and vinylidene isomers for the same transition metal fragment [Cp*Ru(PEt3)2]+

    Journal of the American Chemical Society, Vol. 125, Núm. 11, pp. 3311-3321

2002

  1. Reactions of RuCp and RuCp* allyl carbene complexes: Products derived from activation of phenyl, cyclohexyl, and methyl C-H bonds in PPh3, PCy3, and Cp* ligands

    Organometallics, Vol. 21, Núm. 14, pp. 2912-2920

  2. Reactivity of the electron-rich allenylidene-ruthenium complexes [Cp*Ru{=C=C=C(R)Ph}(dippe)][BPh4] (R = H, Ph). X-ray crystal structure of a novel dicationic ruthenium carbyne (Cp* = C5Me5; dippe = 1,2-bis(diisopropylphosphine)ethane)

    Organometallics, Vol. 21, Núm. 9, pp. 1903-1911

2001

  1. Hydrido(3-hydroxyalkynyl) complexes as intermediates in the activation of propargyl alcohol derivatives by [Cp*RuCl(dippe)] [Cp* = C5Me5, dippe = 1,2-bis(diisopropylphosphanyl)ethane]

    European Journal of Inorganic Chemistry, pp. 2391-2398

2000

  1. Analysis of the solid-state rearrangement of hydrido-alkynyl ruthenium complexes to their vinylidene tautomers

    Monatshefte fur Chemie, Vol. 131, Núm. 12, pp. 1311-1320

  2. Reaction of alkynes with [RuCp(CO)(CH3CN)2]+ and [RuCp*(CO)(CH3CN)2]+. Convenient synthesis of ruthenium cyclopentadienone complexes

    Organometallics, Vol. 19, Núm. 25, pp. 5384-5391

1999

  1. Activation of Alkynols by [Cp*RuCl(PEt3)2]: New Intermediates and Alternative Dehydration Products. X-ray Crystal Structures of [Cp*Ru{=C=CHC(=CH2)Ph}(PEt3)2][BPh 4], [Cp*Ru(=C=C=CPh2)(PEt3)2][BPh 4]

    Organometallics, Vol. 18, Núm. 22, pp. 4563-4573

  2. Activation of alkynols by half-sandwich ruthenium complexes: isolation of hydroxyalkynyl(hydrido) and hydroxyvinylidene derivatives

    Organometallics, Vol. 18, Núm. 6, pp. 950-951

  3. Synthesis and characterization of new ruthenium(II) complexes containing diisopropylmethylphosphine

    Journal of the Chemical Society - Dalton Transactions, pp. 2399-2404